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Any suggestions? Heroine is scared or wary of him at first then falls in love wth him

Scarlet heart ryeo
pin anong
sealed with a kiss
Devil beside you 
Mars
Did you see Hana Yori Dango (Japanese) or Boys Over Flowers (Korean)? If you didn't, check them out and pick one (or even both). 
I second Scarlet Heart and Cheese in the Trap

City Hunter
I Remember You (the male lead is cold to the female lead at the beginning)
Secret (2013)
Suspicious Partner
Beating Again / Falling For Innocence
The Black Devil and The White Prince (prequel) (movie) , it's a very short series but I figured it'd be worth the mention. 
Hana Yori Dango would also be a great pick, it's still one of my favorites to this day
Oh and Boys Over Flowers
100 Days With Mr. Arrogant - movie
rich man poor woman
Second Scarlet Heart and Falling for Innocence. In Falling for Innocence the main guy starts off as a real jerk. 

Kill Me, Heal Me kind of fits in. One of the personalities fits in perfectly ;)
Leh Ratree (Thai. 2015 version)
SOTUS (Thai. A BL story about a hazer and a new student in college.)
+1 for Kill Me Heal Me ( Korean. Sorta fits I don't want to spoil)
+1 for Falling for Innocence ( Korean. It was titled Beating Again on Netflix)