Marvelous Women - both FL and SFL are probably in their thirties and then even older, both in relationships for some time. This is female-centric drama and a rare one where a woman in her thirties starts a new relationship after already being in one for a long time.
NIrvana in Fire - this is not a romance and it's male-cerntric drama, but the female characters are all significantly older and awsome
The Promise of Chang'an - she starts young but for most of the series is much older